MCP๋กœ ์—ฐ๊ฒฐ โ†’

๊ณ„์‚ฐ ์ž…๋ ฅ

์˜ˆ: SOโ‚„ยฒโป์˜ ๊ฒฝ์šฐ, ์‚ฐ์†Œ 4๊ฐœ ร— (โˆ’2) = โˆ’8

๊ณต์‹

๊ด‘๊ณ 

๊ฒฐ๊ณผ

Oxidation State of S
+6
per atom of S
Total from S atoms +6
์•Œ๊ณ  ์žˆ๋Š” ์‚ฐํ™” ์ƒํƒœ์˜ ํ•ฉ -8
์ „์ฒด ์ „ํ•˜ -2

์‚ฐํ™”์ˆ˜๋ž€ ๋ฌด์—‡์ธ๊ฐ€์š”?

์‚ฐํ™”์ˆ˜(๋˜๋Š” ์‚ฐํ™” ์ƒํƒœ)๋Š” ํ•œ ์›์ž๊ฐ€ ๋งบ๊ณ  ์žˆ๋Š” ๋ชจ๋“  ๊ฒฐํ•ฉ์ด ์™„์ „ํžˆ ์ด์˜จ ๊ฒฐํ•ฉ์ด๋ผ๊ณ  ๊ฐ€์ •ํ–ˆ์„ ๋•Œ ๊ทธ ์›์ž๊ฐ€ ๋ ๊ฒŒ ๋˜๋Š” ๊ฐ€์ƒ์˜ ์ „ํ•˜๋ฅผ ๋งํ•ฉ๋‹ˆ๋‹ค. ์‚ฐํ™”ยทํ™˜์› ๋ฐ˜์‘์‹์˜ ๊ท ํ˜•์„ ๋งž์ถ”๊ณ , ํ™”ํ•ฉ๋ฌผ์˜ ์ด๋ฆ„์„ ์ •ํ•˜๋ฉฐ, ์ „์ž์˜ ์ด๋™์„ ์ถ”์ ํ•  ๋•Œ ์“ฐ์ด๋Š” ์ผ์ข…์˜ '์žฅ๋ถ€ ์ •๋ฆฌ' ๋„๊ตฌ๋ผ๊ณ  ํ•  ์ˆ˜ ์žˆ์ฃ . ์ด ๊ณ„์‚ฐ๊ธฐ๋Š” ๋ชจ๋“  ์‚ฐํ™” ์ƒํƒœ์˜ ํ•ฉ์ด ํ•ด๋‹น ํ™”ํ•™์ข…์˜ ์ „์ฒด ์ „ํ•˜์™€ ๊ฐ™๋‹ค๋Š” ๊ธฐ๋ณธ ๊ทœ์น™์„ ์ด์šฉํ•ด, ๋ถ„์ž๋‚˜ ๋‹ค์›์ž ์ด์˜จ ์† ํŠน์ • ์›์†Œ ํ•˜๋‚˜์˜ ๋ฏธ์ง€์˜ ์‚ฐํ™” ์ƒํƒœ๋ฅผ ๊ตฌํ•ด ์ค๋‹ˆ๋‹ค.

Diagram showing electron transfer between two atoms with positive and negative oxidation states labeled
Oxidation numbers track the hypothetical charge on each atom from electron transfer.

๊ณ„์‚ฐ๊ธฐ ์‚ฌ์šฉ ๋ฐฉ๋ฒ•

๊ตฌํ•˜๋ ค๋Š” ์›์†Œ์˜ ๊ธฐํ˜ธ, ํ™”ํ•™์‹ ์•ˆ์— ๊ทธ ์›์†Œ๊ฐ€ ๋ช‡ ๊ฐœ ๋“ค์–ด ์žˆ๋Š”์ง€, ํ™”ํ•™์ข…์˜ ์ „์ฒด ์ „ํ•˜(์ค‘์„ฑ ๋ถ„์ž๋ผ๋ฉด 0), ๊ทธ๋ฆฌ๊ณ  ๋‚˜๋จธ์ง€ ๋ชจ๋“  ์›์ž๊ฐ€ ๊ฐ–๋Š” ์‚ฐํ™” ์ƒํƒœ์˜ ํ•ฉ์„ ์ž…๋ ฅํ•˜์„ธ์š”. ๊ทธ๋Ÿฌ๋ฉด ์„ ํƒํ•œ ์›์†Œ ํ•œ ์›์ž๋‹น ์‚ฐํ™” ์ƒํƒœ๊ฐ€ ๊ณ„์‚ฐ๋˜์–ด ๋‚˜์˜ต๋‹ˆ๋‹ค.

๊ณต์‹ ํ’€์ด

์–ด๋–ค ํ™”ํ•™์ข…์— ๋ฏธ์ง€์˜ ์›์†Œ๊ฐ€ n๊ฐœ ๋“ค์–ด ์žˆ๊ณ  ๊ทธ ์‚ฐํ™” ์ƒํƒœ๊ฐ€ x์ด๋ฉฐ, ๋‚˜๋จธ์ง€ ์›์ž๋“ค์ด ๊ธฐ์—ฌํ•˜๋Š” ์‚ฐํ™” ์ƒํƒœ์˜ ํ•ฉ์ด S๋ผ๋ฉด, ์ „ํ•˜ ๋ณด์กด ๋ฒ•์น™์— ๋”ฐ๋ผ ๋‹ค์Œ์ด ์„ฑ๋ฆฝํ•ฉ๋‹ˆ๋‹ค.

$$n \cdot x + S = Q$$ ์ด๋ฅผ ์ •๋ฆฌํ•˜๋ฉด $$x = \dfrac{Q - S}{n}$$ ์ด๋ฉฐ, ์—ฌ๊ธฐ์„œ \(Q\)๋Š” ์ „์ฒด ์ „ํ•˜์ž…๋‹ˆ๋‹ค.

Bar diagram showing sum of known oxidation states plus unknown equals total charge
The unknown state x is found so all oxidation numbers sum to the overall charge Q.

์˜ˆ์ œ ํ’€์ด: ํ™ฉ์‚ฐ ์ด์˜จ (SOโ‚„ยฒโป)

ํ™ฉ์‚ฐ ์ด์˜จ์—์„œ ์‚ฐ์†Œ๋Š” ๋ณดํ†ต โˆ’2์ž…๋‹ˆ๋‹ค. ์‚ฐ์†Œ๊ฐ€ 4๊ฐœ์ด๋ฏ€๋กœ \(S = 4 \times (-2) = -8\) ์ด ๋˜์ฃ . ์ „์ฒด ์ „ํ•˜๋Š” \(Q = -2\)์ด๊ณ  ํ™ฉ ์›์ž๋Š” \(n = 1\)๊ฐœ์ž…๋‹ˆ๋‹ค. ๋”ฐ๋ผ์„œ $$x = \frac{-2 - (-8)}{1} = +6$$ ์ž…๋‹ˆ๋‹ค. ์ฆ‰, ํ™ฉ์‚ฐ ์ด์˜จ ์† ํ™ฉ์˜ ์‚ฐํ™” ์ƒํƒœ๋Š” +6์ž…๋‹ˆ๋‹ค.

Sulfate ion structure with one central sulfur and four oxygen atoms showing oxidation numbers
In sulfate, four oxygens at -2 and a 2- charge give sulfur an oxidation state of +6.

์ž์ฃผ ๋ฌป๋Š” ์งˆ๋ฌธ

๋ถ€ํ˜ธ ๊ทœ์น™์€ ์–ด๋–ป๊ฒŒ ๋˜๋‚˜์š”? ์–‘(+)์˜ ๊ฐ’์€ ๊ทธ ์›์ž๊ฐ€ ์‚ฐํ™”๋˜์—ˆ์Œ(์ „์ž๋ฅผ ์žƒ์Œ)์„, ์Œ(โˆ’)์˜ ๊ฐ’์€ ํ™˜์›๋˜์—ˆ์Œ(์ „์ž๋ฅผ ์–ป์Œ)์„ ๋œปํ•ฉ๋‹ˆ๋‹ค.

์™œ ๋ถ„์ˆ˜ ํ˜•ํƒœ์˜ ๋‹ต์ด ๋‚˜์˜ค๊ธฐ๋„ ํ•˜๋‚˜์š”? Feโ‚ƒOโ‚„๋‚˜ Sโ‚„Oโ‚†ยฒโป ๊ฐ™์€ ์ผ๋ถ€ ํ™”ํ•ฉ๋ฌผ์—์„œ๋Š” ๊ฐœ๋ณ„ ์›์ž์˜ ์ƒํƒœ๊ฐ€ ์„œ๋กœ ๋‹ฌ๋ผ์„œ, ์‹ค์ œ๋กœ ํ‰๊ท ๊ฐ’์ธ ๋ถ„์ˆ˜ ํ˜•ํƒœ์˜ ์‚ฐํ™” ์ƒํƒœ๊ฐ€ ๋‚˜์˜ค๊ธฐ๋„ ํ•ฉ๋‹ˆ๋‹ค.

ํ”ํžˆ ์•Œ๋ ค์ง„ ์‚ฐํ™”์ˆ˜ ๊ฐ’์—๋Š” ์–ด๋–ค ๊ฒƒ์ด ์žˆ๋‚˜์š”? ์‚ฐ์†Œ๋Š” ๋ณดํ†ต โˆ’2(๊ณผ์‚ฐํ™”๋ฌผ์—์„œ๋Š” โˆ’1), ์ˆ˜์†Œ๋Š” +1(๊ธˆ์† ์ˆ˜์†Œํ™”๋ฌผ์—์„œ๋Š” โˆ’1), ๊ทธ๋ฆฌ๊ณ  1์กฑ ๊ธˆ์†์€ +1์ž…๋‹ˆ๋‹ค.

์ตœ์ข… ์—…๋ฐ์ดํŠธ: