MCP๋กœ ์—ฐ๊ฒฐ โ†’

๊ณ„์‚ฐ ์ž…๋ ฅ

์ตœ๋Œ€ 3๊ฐœ์˜ ๋™์œ„์›์†Œ๋ฅผ ์ž…๋ ฅํ•˜์„ธ์š”. ์‚ฌ์šฉํ•˜์ง€ ์•Š๋Š” ์นธ์€ ๋น„์›Œ ๋‘์„ธ์š”. ์กด์žฌ ๋น„์œจ์˜ ํ•ฉ์€ 100%๊ฐ€ ๋˜์–ด์•ผ ํ•ฉ๋‹ˆ๋‹ค.

๊ณต์‹

๊ด‘๊ณ 

๊ฒฐ๊ณผ

ํ‰๊ท  ์›์ž๋Ÿ‰
35.4527
amu (์›์ž ์งˆ๋Ÿ‰ ๋‹จ์œ„)
์ž…๋ ฅํ•œ ์กด์žฌ ๋น„์œจ ํ•ฉ๊ณ„ 100%

ํ‰๊ท  ์›์ž๋Ÿ‰์ด๋ž€?

์›์†Œ์˜ ํ‰๊ท  ์›์ž๋Ÿ‰(์›์ž๋Ÿ‰์ด๋ผ๊ณ ๋„ ํ•ฉ๋‹ˆ๋‹ค)์€ ์ž์—ฐ์— ์กด์žฌํ•˜๋Š” ๋ชจ๋“  ๋™์œ„์›์†Œ ์งˆ๋Ÿ‰์˜ ๊ฐ€์ค‘ ํ‰๊ท ๊ฐ’์ž…๋‹ˆ๋‹ค. ๊ฐ™์€ ์›์†Œ๋ผ๋„ ๋™์œ„์›์†Œ๋Š” ์ค‘์„ฑ์ž ์ˆ˜๊ฐ€ ๋‹ค๋ฅด๊ธฐ ๋•Œ๋ฌธ์— ์งˆ๋Ÿ‰์— ์ฐจ์ด๊ฐ€ ์ƒ๊น๋‹ˆ๋‹ค. ์ฃผ๊ธฐ์œจํ‘œ์— ์ ํžŒ ์›์ž๋Ÿ‰ ๊ฐ’์€ ๊ฐ ๋™์œ„์›์†Œ๊ฐ€ ์ž์—ฐ๊ณ„์— ์–ผ๋งˆ๋‚˜ ์กด์žฌํ•˜๋Š”์ง€๋ฅผ ๊ทธ ์ƒ๋Œ€์  ์กด์žฌ ๋น„์œจ๋กœ ๊ฐ€์ค‘ํ•˜์—ฌ ๋ฐ˜์˜ํ•œ ๊ฒƒ์ž…๋‹ˆ๋‹ค.

Two isotopes on a balance combining into a weighted average atomic mass
Average atomic mass is the abundance-weighted average of an element's isotopes.

๊ณ„์‚ฐ๊ธฐ ์‚ฌ์šฉ ๋ฐฉ๋ฒ•

๊ฐ ๋™์œ„์›์†Œ์˜ ์งˆ๋Ÿ‰(์›์ž ์งˆ๋Ÿ‰ ๋‹จ์œ„, amu)๊ณผ ์ž์—ฐ ์กด์žฌ ๋น„์œจ(%)์„ ์ž…๋ ฅํ•˜์„ธ์š”. ์ตœ๋Œ€ 3๊ฐœ๊นŒ์ง€ ์ž…๋ ฅํ•  ์ˆ˜ ์žˆ์œผ๋ฉฐ, ์‚ฌ์šฉํ•˜์ง€ ์•Š๋Š” ์นธ์€ ๋น„์›Œ ๋‘๋ฉด ๋ฉ๋‹ˆ๋‹ค. ์กด์žฌ ๋น„์œจ์˜ ํ•ฉ์€ ๋Œ€๋žต 100%๊ฐ€ ๋˜์–ด์•ผ ํ•ฉ๋‹ˆ๋‹ค. ๊ณ„์‚ฐํ•˜๊ธฐ ๋ฒ„ํŠผ์„ ๋ˆ„๋ฅด๋ฉด ์›์†Œ์˜ ํ‰๊ท  ์›์ž๋Ÿ‰์ด ๋‚˜์˜ต๋‹ˆ๋‹ค.

๊ณต์‹ ํ’€์ด

ํ‰๊ท  ์›์ž๋Ÿ‰์€ ๋‹ค์Œ๊ณผ ๊ฐ™์ด ๊ณ„์‚ฐํ•ฉ๋‹ˆ๋‹ค.

$$\text{ํ‰๊ท  ์›์ž๋Ÿ‰} = \sum (\text{๋™์œ„์›์†Œ ์งˆ๋Ÿ‰} \times \text{๋ถ„์œจ ์กด์žฌ ๋น„์œจ})$$

์—ฌ๊ธฐ์„œ ๋ถ„์œจ ์กด์žฌ ๋น„์œจ์€ ์กด์žฌ ๋น„์œจ(%)์„ 100์œผ๋กœ ๋‚˜๋ˆˆ ๊ฐ’์ž…๋‹ˆ๋‹ค. ์ฆ‰, ๊ฐ ๋™์œ„์›์†Œ์˜ ์งˆ๋Ÿ‰์— ์†Œ์ˆ˜๋กœ ๋‚˜ํƒ€๋‚ธ ์กด์žฌ ๋น„์œจ์„ ๊ณฑํ•œ ๋’ค, ๊ทธ ๊ฒฐ๊ณผ๋“ค์„ ๋ชจ๋‘ ๋”ํ•˜๋ฉด ๋ฉ๋‹ˆ๋‹ค. ์ด๋ ‡๊ฒŒ ํ•˜๋ฉด ์ž์—ฐ๊ณ„์— ์กด์žฌํ•˜๋Š” ๊ทธ๋Œ€๋กœ์˜ ์›์†Œ๋ฅผ ๋Œ€ํ‘œํ•˜๋Š” ํ•˜๋‚˜์˜ ๊ฐ€์ค‘ ํ‰๊ท ๊ฐ’์ด ๊ตฌํ•ด์ง‘๋‹ˆ๋‹ค.

$$\bar{M} = \sum_{i} m_i \times \frac{a_i}{100}$$

Diagram of isotope mass times fractional abundance terms summed together
Each isotope's mass is multiplied by its fractional abundance, then summed.

์˜ˆ์ œ ํ’€์ด: ์—ผ์†Œ(Cl)

์—ผ์†Œ์—๋Š” ์•ˆ์ •ํ•œ ๋™์œ„์›์†Œ๊ฐ€ ๋‘ ๊ฐ€์ง€ ์žˆ์Šต๋‹ˆ๋‹ค. ์—ผ์†Œ-35์˜ ์งˆ๋Ÿ‰์€ \(34.96885\) amu์ด๊ณ  ์กด์žฌ ๋น„์œจ์€ 75.77%, ์—ผ์†Œ-37์˜ ์งˆ๋Ÿ‰์€ \(36.96590\) amu์ด๊ณ  ์กด์žฌ ๋น„์œจ์€ 24.23%์ž…๋‹ˆ๋‹ค.

$$(34.96885 \times 0.7577) + (36.96590 \times 0.2423) = 26.4959 + 8.9568 = 35.4527 \text{ amu}$$

์ด ๊ฐ’์€ ์ฃผ๊ธฐ์œจํ‘œ์— ํ‘œ์‹œ๋œ ์—ผ์†Œ์˜ ์›์ž๋Ÿ‰์ธ ์•ฝ 35.45 amu์™€ ์ผ์น˜ํ•ฉ๋‹ˆ๋‹ค.

Chlorine-35 and chlorine-37 shown in roughly 75 to 25 percent proportions
Chlorine's two isotopes (Cl-35 and Cl-37) yield an average mass near 35.45.

์ผ๋ฐ˜ ์›์†Œ์˜ ๋™์œ„์›์†Œ ์งˆ๋Ÿ‰ ๋ฐ ์ฒœ์—ฐ ์กด์žฌ๋น„

์•„๋ž˜ ๊ฐ’๋“ค์€ IUPAC/CIAAW์—์„œ ๋ฐœํ‘œํ•œ ํ‘œ์ค€ ๋™์œ„์›์†Œ ์งˆ๋Ÿ‰(ํ†ต์ผ ์›์ž ์งˆ๋Ÿ‰ ๋‹จ์œ„, u)๊ณผ ๋Œ€ํ‘œ ์ฒœ์—ฐ ๋ฐฑ๋ถ„์œจ ์กด์žฌ๋น„์ž…๋‹ˆ๋‹ค. ์กด์žฌ๋น„๋Š” ์ง€๊ตฌ ํ‘œ๋ณธ ์‚ฌ์ด์—์„œ ์•ฝ๊ฐ„์”ฉ ๋ณ€ํ•˜๋ฏ€๋กœ, ํ‘œ์‹œ๋œ ์ˆ˜์น˜๋Š” ๋„๋ฆฌ ์‚ฌ์šฉ๋˜๋Š” ๋Œ€ํ‘œ๊ฐ’์ž…๋‹ˆ๋‹ค. ๊ฐ ์›์†Œ์˜ ์•ˆ์ • ๋™์œ„์›์†Œ๊ฐ€ ๋‚˜์—ด๋˜๋ฉฐ, ํ•œ ์›์†Œ์˜ ๋™์œ„์›์†Œ๋“ค์˜ ์กด์žฌ๋น„๋Š” 100%์ž…๋‹ˆ๋‹ค.

์›์†Œ ๋™์œ„์›์†Œ ๋™์œ„์›์†Œ ์งˆ๋Ÿ‰ (u) ์กด์žฌ๋น„ (%)
์ˆ˜์†Œ ยนH 1.007825 99.9885
ยฒH (D) 2.014102 0.0115
๋ถ•์†Œ ยนโฐB 10.012937 19.9
ยนยนB 11.009305 80.1
ํƒ„์†Œ ยนยฒC 12.000000 98.93
ยนยณC 13.003355 1.07
๋งˆ๊ทธ๋„ค์Š˜ ยฒโดMg 23.985042 78.99
ยฒโตMg 24.985837 10.00
ยฒโถMg 25.982593 11.01
๊ทœ์†Œ ยฒโธSi 27.976927 92.23
ยฒโนSi 28.976495 4.68
ยณโฐSi 29.973770 3.09
์—ผ์†Œ ยณโตCl 34.968853 75.76
ยณโทCl 36.965903 24.24
๊ตฌ๋ฆฌ โถยณCu 62.929598 69.15
โถโตCu 64.927790 30.85
๋ธŒ๋กœ๋ฏผ โทโนBr 78.918338 50.69
โธยนBr 80.916290 49.31

์ฃผ์š” ์šฉ์–ด ๋ฐ ์ •์˜

๋™์œ„์›์†Œ
๊ฐ™์€ ์›์†Œ(๊ฐ™์€ ์ˆ˜์˜ ์–‘์„ฑ์ž)์˜ ์›์ž์ด์ง€๋งŒ ์ค‘์„ฑ์ž์˜ ์ˆ˜๊ฐ€ ๋‹ค๋ฅด๋ฉฐ, ๋”ฐ๋ผ์„œ ์งˆ๋Ÿ‰์ด ๋‹ค๋ฆ…๋‹ˆ๋‹ค. ์˜ˆ๋ฅผ ๋“ค์–ด, ยณโตCl๊ณผ ยณโทCl์€ ๋ชจ๋‘ ์—ผ์†Œ์ž…๋‹ˆ๋‹ค.
์งˆ๋Ÿ‰์ˆ˜ (A)
ํ•ต ๋‚ด ์–‘์„ฑ์ž์™€ ์ค‘์„ฑ์ž์˜ ์ด ๊ฐœ์ˆ˜๋กœ, ํ•ต์ข… ๊ธฐํ˜ธ์—์„œ ์œ„์ฒจ์ž๋กœ ํ‘œ๊ธฐ๋ฉ๋‹ˆ๋‹ค(์˜ˆ: ยนยฒC์˜ 12). ์ •์ˆ˜์ด๋ฉฐ ๋™์œ„์›์†Œ๋ฅผ ๊ตฌ๋ถ„ํ•ฉ๋‹ˆ๋‹ค.
์›์ž ์งˆ๋Ÿ‰ ๋‹จ์œ„ (amu, u, ๋˜๋Š” ๋‹ฌํ†ค)
์›์ž ๊ทœ๋ชจ์˜ ์งˆ๋Ÿ‰์— ๋Œ€ํ•œ ํ‘œ์ค€ ๋‹จ์œ„๋กœ, ์ค‘์„ฑ ยนยฒC ์›์ž ์งˆ๋Ÿ‰์˜ ์ •ํ™•ํžˆ 1/12๋กœ ์ •์˜๋ฉ๋‹ˆ๋‹ค. 1 u โ‰ˆ 1.66054 ร— 10โปยฒโด g์ž…๋‹ˆ๋‹ค. ๊ธฐํ˜ธ amu, u, ๋ฐ Da (๋‹ฌํ†ค)๋Š” ๋ชจ๋‘ ๊ฐ™์€ ๋‹จ์œ„๋ฅผ ๋‚˜ํƒ€๋ƒ…๋‹ˆ๋‹ค.
๋™์œ„์›์†Œ ์งˆ๋Ÿ‰
๋‹จ์ผ ๋™์œ„์›์†Œ์˜ ์‹ค์ œ ์ธก์ • ์งˆ๋Ÿ‰์„ u๋กœ ํ‘œํ˜„ํ•œ ๊ฒƒ์ž…๋‹ˆ๋‹ค. ํ•ต ๊ฒฐํ•ฉ ์—๋„ˆ์ง€์™€ ์–‘์„ฑ์ž/์ค‘์„ฑ์ž ์งˆ๋Ÿ‰ ์ฐจ์ด๋กœ ์ธํ•ด ์งˆ๋Ÿ‰์ˆ˜์™€ ๊ฑฐ์˜ ๊ฐ™์ง€๋งŒ ์ •ํ™•ํžˆ ๊ฐ™์ง€๋Š” ์•Š์Šต๋‹ˆ๋‹ค(์˜ˆ: ยนยนB์˜ ๋™์œ„์›์†Œ ์งˆ๋Ÿ‰์€ 11.0093 u).
๋ฐฑ๋ถ„์œจ ์กด์žฌ๋น„
์›์†Œ์˜ ์›์ž ์ค‘ ์ฃผ์–ด์ง„ ๋™์œ„์›์†Œ์˜ ๋น„์œจ๋กœ, ๋ฐฑ๋ถ„์œจ(0โ€“100%)๋กœ ํ‘œํ˜„๋ฉ๋‹ˆ๋‹ค. ํ•œ ์›์†Œ์˜ ๋ชจ๋“  ๋™์œ„์›์†Œ์˜ ์กด์žฌ๋น„๋Š” ํ•ฉ์ณ์ ธ 100%๊ฐ€ ๋ฉ๋‹ˆ๋‹ค.
๋ถ„์ˆ˜ ์กด์žฌ๋น„
๊ฐ™์€ ์–‘์„ ๋ฐฑ๋ถ„์œจ ๋Œ€์‹  ์‹ญ์ง„ ๋ถ„์ˆ˜(0โ€“1)๋กœ ํ‘œํ˜„ํ•œ ๊ฒƒ์ž…๋‹ˆ๋‹ค. ์ฆ‰, ๋ฐฑ๋ถ„์œจ ์กด์žฌ๋น„๋ฅผ 100์œผ๋กœ ๋‚˜๋ˆˆ ๊ฒƒ์ž…๋‹ˆ๋‹ค. ๋ถ„์ˆ˜ ์กด์žฌ๋น„๋ฅผ ์‚ฌ์šฉํ•˜๋ฉด 100์œผ๋กœ ๋‚˜๋ˆ„์ง€ ์•Š๊ณ  ๊ฐ€์ค‘ ํ•ฉ์„ ์ง์ ‘ ๊ณ„์‚ฐํ•  ์ˆ˜ ์žˆ์Šต๋‹ˆ๋‹ค.
ํ‰๊ท  ์›์ž ์งˆ๋Ÿ‰ (์›์ž๋Ÿ‰)
์›์†Œ์˜ ๋™์œ„์›์†Œ ์งˆ๋Ÿ‰์˜ ์กด์žฌ๋น„ ๊ฐ€์ค‘ ํ‰๊ท ์œผ๋กœ, ๋‹จ์œ„๋Š” u์ž…๋‹ˆ๋‹ค. ์ด๋Š” ์ฃผ๊ธฐ์œจํ‘œ์— ๋‚˜ํƒ€๋‚˜๋Š” ๊ฐ’์ด๋ฉฐ ๋ชฐ ๊ณ„์‚ฐ์—์„œ ๋ชฐ์งˆ๋Ÿ‰(g/mol)์œผ๋กœ ์‚ฌ์šฉ๋ฉ๋‹ˆ๋‹ค. ์ด๋Š” \(\bar{M} = \sum (\text{๋™์œ„์›์†Œ ์งˆ๋Ÿ‰} \times \text{๋ถ„์ˆ˜ ์กด์žฌ๋น„})\)๋กœ ๊ณ„์‚ฐ๋ฉ๋‹ˆ๋‹ค.

์ž์ฃผ ๋ฌป๋Š” ์งˆ๋ฌธ

ํ‰๊ท ๊ฐ’์ด ์™œ ์ •์ˆ˜๋กœ ๋”ฑ ๋–จ์–ด์ง€์ง€ ์•Š๋‚˜์š”? ์กด์žฌ ๋น„์œจ์ด ์„œ๋กœ ๋‹ค๋ฅธ ๋™์œ„์›์†Œ๋“ค์˜ ๊ฐ€์ค‘ ํ‰๊ท ์ด๊ธฐ ๋•Œ๋ฌธ์— ๊ฒฐ๊ณผ๊ฐ€ ๊น”๋”ํ•œ ์ •์ˆ˜๋กœ ๋‚˜์˜ค๋Š” ๊ฒฝ์šฐ๋Š” ๊ฑฐ์˜ ์—†์Šต๋‹ˆ๋‹ค.

์กด์žฌ ๋น„์œจ์˜ ํ•ฉ์ด ๋ฐ˜๋“œ์‹œ 100%์—ฌ์•ผ ํ•˜๋‚˜์š”? ๋„ค. ํ•œ ์›์†Œ์˜ ๋ชจ๋“  ๋™์œ„์›์†Œ ์ž์—ฐ ์กด์žฌ ๋น„์œจ์„ ๋”ํ•˜๋ฉด 100%๊ฐ€ ๋˜์–ด์•ผ ํ•ฉ๋‹ˆ๋‹ค. ๋ฐ˜์˜ฌ๋ฆผ์œผ๋กœ ์ธํ•œ ์ž‘์€ ์˜ค์ฐจ๋Š” ๊ดœ์ฐฎ์Šต๋‹ˆ๋‹ค.

๊ฒฐ๊ณผ์˜ ๋‹จ์œ„๋Š” ๋ฌด์—‡์ธ๊ฐ€์š”? ์›์ž ์งˆ๋Ÿ‰ ๋‹จ์œ„(amu)์ด๋ฉฐ, u ๋˜๋Š” ๋Œํ„ด(Dalton)์œผ๋กœ๋„ ํ‘œ๊ธฐํ•ฉ๋‹ˆ๋‹ค.

์ตœ์ข… ์—…๋ฐ์ดํŠธ: