MCP๋กœ ์—ฐ๊ฒฐ โ†’

๊ณ„์‚ฐ ์ž…๋ ฅ

V1๊ณผ V2๋Š” ๊ฐ™์€ ๋‹จ์œ„๋ฅผ ์จ์•ผ ํ•ฉ๋‹ˆ๋‹ค (์˜ˆ: ๋‘˜ ๋‹ค mL ๋˜๋Š” ๋‘˜ ๋‹ค L).

๊ณต์‹

๊ด‘๊ณ 

๊ฒฐ๊ณผ

ํฌ์„ ํ›„ pH
2
pH ๋‹จ์œ„
ํฌ์„ ๋†๋„ (C2) 0.01 mol/L
pOH 12

์ด ๊ณ„์‚ฐ๊ธฐ์˜ ๊ธฐ๋Šฅ

์ด ๋„๊ตฌ๋Š” ๊ฐ•์‚ฐ ๋˜๋Š” ๊ฐ•์—ผ๊ธฐ๋ฅผ ํฌ์„ํ•œ ๋’ค์˜ pH๋ฅผ ๊ตฌํ•ด ์ค๋‹ˆ๋‹ค. ๊ฐ•์‚ฐ(HCl, HNOโ‚ƒ, ๊ทธ๋ฆฌ๊ณ  1์ฐจ ๊ทผ์‚ฌ๋กœ Hโ‚‚SOโ‚„)๊ณผ ๊ฐ•์—ผ๊ธฐ(NaOH, KOH)๋Š” ๋ฌผ์—์„œ ์™„์ „ํžˆ ์ด์˜จํ™”๋˜๋ฏ€๋กœ, ์ˆ˜์†Œ ์ด์˜จ์ด๋‚˜ ์ˆ˜์‚ฐํ™” ์ด์˜จ์˜ ๋†๋„๊ฐ€ ์šฉ์งˆ์˜ ๋ชฐ ๋†๋„์™€ ๊ฐ™์•„์ง‘๋‹ˆ๋‹ค. ์šฉ์•ก์„ ํฌ์„ํ•˜๋ฉด ์ด ๋†๋„๊ฐ€ ๋‚ฎ์•„์ง€๊ณ  pH๋Š” 7์— ๊ฐ€๊นŒ์›Œ์ง‘๋‹ˆ๋‹ค.

์ง„ํ•œ ์‚ฐ์„ ๋ฌผ๋กœ ํฌ์„ํ•ด ๋” ํฐ ๋ถ€ํ”ผ๋กœ ๋งŒ๋“œ๋Š” ๋ชจ์Šต์„ ๋ณด์—ฌ์ฃผ๋Š” ๋‘ ๊ฐœ์˜ ๋น„์ปค
ํฌ์„์€ ๊ฐ™์€ ์–‘์˜ ์‚ฐ์„ ๋” ํฐ ๋ถ€ํ”ผ์— ํผ๋œจ๋ ค ๋†๋„๋ฅผ ๋‚ฎ์ถฅ๋‹ˆ๋‹ค.

์‚ฌ์šฉ ๋ฐฉ๋ฒ•

๋จผ์ € ์šฉ์•ก์ด ๊ฐ•์‚ฐ์ธ์ง€ ๊ฐ•์—ผ๊ธฐ์ธ์ง€ ์„ ํƒํ•ฉ๋‹ˆ๋‹ค. ๊ทธ๋‹ค์Œ ์ดˆ๊ธฐ ๋ชฐ ๋†๋„ C1(mol/L), ์ดˆ๊ธฐ ๋ถ€ํ”ผ V1, ๊ทธ๋ฆฌ๊ณ  ์šฉ๋งค๋ฅผ ๋”ํ•œ ๋’ค์˜ ์ตœ์ข… ๋ถ€ํ”ผ V2๋ฅผ ์ž…๋ ฅํ•˜์„ธ์š”. V1๊ณผ V2๋Š” ๋ฐ˜๋“œ์‹œ ๊ฐ™์€ ๋‹จ์œ„๋ฅผ ์จ์•ผ ํ•ฉ๋‹ˆ๋‹ค. ๊ณ„์‚ฐ๊ธฐ๋Š” ํฌ์„๋œ ๋†๋„ C2์™€ ๊ทธ์— ๋”ฐ๋ฅธ pH, pOH๋ฅผ ์•Œ๋ ค ์ค๋‹ˆ๋‹ค.

๊ณต์‹ ํ’€์ด

ํฌ์„์„ ํ•ด๋„ ์šฉ์งˆ์˜ ๋ชฐ์ˆ˜๋Š” ๋ณ€ํ•˜์ง€ ์•Š์œผ๋ฏ€๋กœ, ์ž˜ ์•Œ๋ ค์ง„ ๊ด€๊ณ„์‹ \(\text{C}_1\cdot\text{V}_1 = \text{C}_2\cdot\text{V}_2\)๊ฐ€ ์„ฑ๋ฆฝํ•ฉ๋‹ˆ๋‹ค. ๋”ฐ๋ผ์„œ \(\text{C}_2 = \dfrac{\text{C}_1\cdot\text{V}_1}{\text{V}_2}\)๊ฐ€ ๋ฉ๋‹ˆ๋‹ค.

$$\text{pH} = -\log_{10}(C_2) \\[1.5em] \text{where}\quad C_2 = \frac{\text{C}_1 \cdot \text{V}_1}{\text{V}_2}$$

1๊ฐ€ ๊ฐ•์‚ฐ์˜ ๊ฒฝ์šฐ \([\text{H}^+] = C_2\)์ด๊ณ  \(\text{pH} = -\log_{10}(C_2)\)์ž…๋‹ˆ๋‹ค. ๊ฐ•์—ผ๊ธฐ์˜ ๊ฒฝ์šฐ \([\text{OH}^-] = C_2\)์ด๋ฏ€๋กœ \(\text{pOH} = -\log_{10}(C_2)\)์ด๊ณ , \(\text{pH} = 14 - \text{pOH}\)์ž…๋‹ˆ๋‹ค(๋ฌผ์˜ ์ด์˜จ๊ณฑ pKw = 14์ธ 25โ„ƒ ๊ธฐ์ค€).

$$\text{pH} = 14 - \bigl(-\log_{10}(C_2)\bigr) \\[1.5em] \text{where}\quad C_2 = \frac{\text{C}_1 \cdot \text{V}_1}{\text{V}_2}$$
์‚ฐ์„ฑ, ์ค‘์„ฑ, ์—ผ๊ธฐ์„ฑ ๊ตฌ๊ฐ„์ด ์žˆ๋Š” 0๋ถ€ํ„ฐ 14๊นŒ์ง€์˜ pH ์ฒ™๋„๋ฅผ ๋‚˜ํƒ€๋‚ธ ์ˆ˜์ง์„ 
pH ์ฒ™๋„: ๊ฐ’์ด ๋‚ฎ์œผ๋ฉด ์‚ฐ์„ฑ, 7์€ ์ค‘์„ฑ, ๋†’์œผ๋ฉด ์—ผ๊ธฐ์„ฑ์ž…๋‹ˆ๋‹ค.

๊ณ„์‚ฐ ์˜ˆ์‹œ

0.1 mol/L HCl 10 mL๋ฅผ 100 mL๊ฐ€ ๋˜๋„๋ก ํฌ์„ํ•œ๋‹ค๊ณ  ํ•ฉ์‹œ๋‹ค.

$$C_2 = \frac{0.1 \times 10}{100} = 0.01 \text{ mol/L}$$

์ด๊ณ ,

$$\text{pH} = -\log_{10}(0.01) = 2$$

์ž…๋‹ˆ๋‹ค. ์ฒ˜์Œ์— pH 1์ด๋˜ ์‚ฐ์ด 10๋ฐฐ ํฌ์„ ํ›„ pH 2๊ฐ€ ๋œ ๊ฒƒ์ž…๋‹ˆ๋‹ค.

์ž์ฃผ ๋ฌป๋Š” ์งˆ๋ฌธ

์•ฝ์‚ฐ์—๋„ ์ ์šฉ๋˜๋‚˜์š”? ์•„๋‹ˆ์š”. ์•ฝ์‚ฐ๊ณผ ์•ฝ์—ผ๊ธฐ๋Š” ๋ถ€๋ถ„์ ์œผ๋กœ๋งŒ ์ด์˜จํ™”๋˜๊ธฐ ๋•Œ๋ฌธ์—, pH๋ฅผ ๊ตฌํ•˜๋ ค๋ฉด ์‚ฐ ํ•ด๋ฆฌ ์ƒ์ˆ˜ Ka์™€ ํ‰ํ˜• ๊ณ„์‚ฐ์ด ํ•„์š”ํ•ฉ๋‹ˆ๋‹ค.

์™œ ๋งŽ์ด ํฌ์„ํ• ์ˆ˜๋ก pH๊ฐ€ 7์— ๊ฐ€๊นŒ์›Œ์ง€๋‚˜์š”? ๋†๋„๊ฐ€ ๋‚ฎ์•„์งˆ์ˆ˜๋ก ๋ฌผ์˜ ์ž์ฒด ์ด์˜จํ™”๊ฐ€ ๋ฏธ์น˜๋Š” ์˜ํ–ฅ์ด ์ปค์ง€๊ธฐ ๋•Œ๋ฌธ์ž…๋‹ˆ๋‹ค. ์ด ๊ฐ„๋‹จํ•œ ๋ชจ๋ธ์€ ์šฉ์งˆ์ด ์ง€๋ฐฐ์ ์ด๋ผ๊ณ  ๊ฐ€์ •ํ•˜์ง€๋งŒ, ๋†๋„๊ฐ€ ๊ทน๋„๋กœ ๋‚ฎ์•„์ง€๋ฉด ์‹ค์ œ pH๋Š” 7 ๋ถ€๊ทผ์—์„œ ๋ฉˆ์ถฅ๋‹ˆ๋‹ค.

๊ฐ€์ •ํ•œ ์˜จ๋„๋Š” ๋ช‡ ๋„์ธ๊ฐ€์š”? 25โ„ƒ์ด๋ฉฐ, ์ด๋•Œ pKw = 14๋กœ pH์™€ pOH๋ฅผ ์„œ๋กœ ๋ณ€ํ™˜ํ•ฉ๋‹ˆ๋‹ค.

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