MCP๋กœ ์—ฐ๊ฒฐ โ†’

๊ณ„์‚ฐ ์ž…๋ ฅ

๊ณต์‹

๊ด‘๊ณ 

๊ฒฐ๊ณผ

ํ‘œ์ค€ ๊น์Šค ์ž์œ ์—๋„ˆ์ง€ ๋ณ€ํ™” (ฮ”Gยฐ)
-17.124
kJ/mol
ฮ”Gยฐ (J/mol) -17,124.03
ln(K) 6.9078
๊ธฐ์ฒด ์ƒ์ˆ˜ R 8.314462618 J/(molยทK)

์ด ๊ณ„์‚ฐ๊ธฐ๋Š” ๋ฌด์—‡์„ ํ•˜๋‚˜์š”

์ด ๋„๊ตฌ๋Š” ํ™”ํ•™ ๋ฐ˜์‘์˜ ํ‰ํ˜•์ƒ์ˆ˜ K์™€ ์ ˆ๋Œ€์˜จ๋„ T๋กœ๋ถ€ํ„ฐ ํ‘œ์ค€ ๊น์Šค ์ž์œ ์—๋„ˆ์ง€ ๋ณ€ํ™”(ฮ”Gยฐ)๋ฅผ ๊ณ„์‚ฐํ•ฉ๋‹ˆ๋‹ค. \(\Delta G^{\circ} = -RT \ln K\)๋ผ๋Š” ๊ด€๊ณ„์‹์€ ์—ด์—ญํ•™๊ณผ ํ™”ํ•™ ํ‰ํ˜•์„ ์ด์–ด ์ฃผ๋Š” ํ•ต์‹ฌ ๊ณต์‹์œผ๋กœ, ํ‘œ์ค€ ์ƒํƒœ์—์„œ ๋ฐ˜์‘์ด ์ž๋ฐœ์ ์œผ๋กœ ์ผ์–ด๋‚˜๋Š”์ง€๋ฅผ ์•Œ๋ ค ์ค๋‹ˆ๋‹ค. ฮ”Gยฐ๊ฐ€ ์Œ์ˆ˜(K > 1)์ด๋ฉด ์ƒ์„ฑ๋ฌผ ์ชฝ์œผ๋กœ ์น˜์šฐ์นœ ๋ฐ˜์‘, ฮ”Gยฐ๊ฐ€ ์–‘์ˆ˜(K < 1)์ด๋ฉด ๋ฐ˜์‘๋ฌผ ์ชฝ์œผ๋กœ ์น˜์šฐ์นœ ๋ฐ˜์‘์ž„์„ ์˜๋ฏธํ•ฉ๋‹ˆ๋‹ค.

์‚ฌ์šฉ ๋ฐฉ๋ฒ•

๋ฌด์ฐจ์› ํ‰ํ˜•์ƒ์ˆ˜ K(๋ฐ˜๋“œ์‹œ 0๋ณด๋‹ค ์ปค์•ผ ํ•ฉ๋‹ˆ๋‹ค)์™€ ์ผˆ๋นˆ(K) ๋‹จ์œ„ ์˜จ๋„๋ฅผ ์ž…๋ ฅํ•˜์„ธ์š”. 25 ยฐC๋Š” 298.15 K์— ํ•ด๋‹นํ•ฉ๋‹ˆ๋‹ค. ๊ณ„์‚ฐ๊ธฐ๋Š” ๋Œ€ํ‘œ ๊ฒฐ๊ณผ์ธ kJ/mol๊ณผ ํ•จ๊ป˜ J/mol ๋‹จ์œ„์˜ ฮ”Gยฐ๋ฅผ ์ œ๊ณตํ•˜๋ฉฐ, ์ค‘๊ฐ„ ๊ณผ์ •์„ ํ™•์ธํ•  ์ˆ˜ ์žˆ๋„๋ก \(\ln(K)\) ๊ฐ’๋„ ํ•จ๊ป˜ ๋ณด์—ฌ ์ค๋‹ˆ๋‹ค.

๊ณต์‹ ์ž์„ธํžˆ ๋ณด๊ธฐ

๊ณต์‹์€ ๋‹ค์Œ๊ณผ ๊ฐ™์Šต๋‹ˆ๋‹ค.

$$\Delta G^{\circ} = -RT \ln K$$

์—ฌ๊ธฐ์„œ \(R = 8.314462618\ \text{J/(mol}\cdot\text{K)}\)๋Š” ๊ธฐ์ฒด ์ƒ์ˆ˜, T๋Š” ์ผˆ๋นˆ ๋‹จ์œ„์˜ ์ ˆ๋Œ€์˜จ๋„, K๋Š” ํ‰ํ˜•์ƒ์ˆ˜์ž…๋‹ˆ๋‹ค. \(\ln K\)๋Š” ๋ฌด์ฐจ์›์ด๊ณ  RT๊ฐ€ J/mol ๋‹จ์œ„๋ฅผ ๊ฐ€์ง€๋ฏ€๋กœ ฮ”Gยฐ๋Š” ์ค„(joule) ๋‹จ์œ„๋กœ ๋‚˜์˜ต๋‹ˆ๋‹ค. ์ด ๊ฐ’์„ 1000์œผ๋กœ ๋‚˜๋ˆ„๋ฉด kJ/mol๋กœ ํ™˜์‚ฐ๋ฉ๋‹ˆ๋‹ค.

Curve showing ฮ”Gยฐ decreasing as K increases, crossing zero at K equals 1
ฮ”Gยฐ is negative when K > 1 (products favored) and positive when K < 1 (reactants favored), crossing zero at K = 1.

๊ณ„์‚ฐ ์˜ˆ์‹œ

T = 298.15 K์—์„œ K = 1000์ด๋ผ๊ณ  ๊ฐ€์ •ํ•ด ๋ด…์‹œ๋‹ค. ์ด๋•Œ \(\ln(1000) \approx 6.907755\)์ž…๋‹ˆ๋‹ค.

$$\Delta G^{\circ} = -(8.314462618)(298.15)(6.907755) \approx -17{,}123\ \text{J/mol} \approx -17.12\ \text{kJ/mol}$$

ํฐ ์–‘์ˆ˜์˜ K์™€ ์Œ์ˆ˜์˜ ฮ”Gยฐ๋Š” ๋ฐ˜์‘์ด ๊ฐ•ํ•˜๊ฒŒ ์ƒ์„ฑ๋ฌผ ์ชฝ์œผ๋กœ ์น˜์šฐ์ณ ์žˆ์Œ์„ ํ™•์ธํ•ด ์ค๋‹ˆ๋‹ค.

Energy level diagram showing products lower than reactants with a downward ฮ”Gยฐ arrow
A spontaneous reaction releases free energy: products lie below reactants and the equilibrium favors products.

์ž์ฃผ ๋ฌป๋Š” ์งˆ๋ฌธ

์™œ ์˜จ๋„๋ฅผ ์ผˆ๋นˆ์œผ๋กœ ๋„ฃ์–ด์•ผ ํ•˜๋‚˜์š”? ์—ด์—ญํ•™ ์‹์—๋Š” ์ ˆ๋Œ€์˜จ๋„๊ฐ€ ํ•„์š”ํ•ฉ๋‹ˆ๋‹ค. ์„ญ์”จ ์˜จ๋„์— 273.15๋ฅผ ๋”ํ•˜๋ฉด ์ผˆ๋นˆ์œผ๋กœ ๋ณ€ํ™˜๋ฉ๋‹ˆ๋‹ค.

K๊ฐ€ 1์ด๋ฉด ์–ด๋–ป๊ฒŒ ๋˜๋‚˜์š”? \(\ln(1) = 0\)์ด๋ฏ€๋กœ \(\Delta G^{\circ} = 0\)์ด ๋ฉ๋‹ˆ๋‹ค. ์ฆ‰ ํ‘œ์ค€ ์ƒํƒœ์—์„œ ๋ฐ˜์‘์ด ์ •ํ™•ํžˆ ํ‰ํ˜•์— ์žˆ์œผ๋ฉฐ, ์–ด๋А ์ชฝ์œผ๋กœ๋„ ์ถ”์ง„๋ ฅ์ด ์—†๋Š” ์ƒํƒœ์ž…๋‹ˆ๋‹ค.

K๊ฐ€ ์Œ์ˆ˜๋‚˜ 0์ด ๋  ์ˆ˜ ์žˆ๋‚˜์š”? ์•„๋‹™๋‹ˆ๋‹ค. ๋†๋„์™€ ๋ถ€๋ถ„์••์€ ํ•ญ์ƒ ์–‘์ˆ˜์ด๋ฏ€๋กœ ํ‰ํ˜•์ƒ์ˆ˜๋„ ์–ธ์ œ๋‚˜ ์–‘์ˆ˜์ž…๋‹ˆ๋‹ค. ๋”ฐ๋ผ์„œ \(K \le 0\)์ผ ๋•Œ๋Š” \(\ln K\)๊ฐ€ ์ •์˜๋˜์ง€ ์•Š์Šต๋‹ˆ๋‹ค.

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