MCP๋กœ ์—ฐ๊ฒฐ โ†’

๊ณ„์‚ฐ ์ž…๋ ฅ

๊ณต์‹

๊ด‘๊ณ 

๊ฒฐ๊ณผ

๊ธฐ์ฒด 1์˜ ์†๋„ (rateโ‚)
2.8274
rateโ‚‚์™€ ๋™์ผํ•œ ๋‹จ์œ„
์†๋„๋น„ (rateโ‚ / rateโ‚‚) 2.82742

๋ถ„์ถœ ์†๋„ ๊ณ„์‚ฐ๊ธฐ๋ž€?

๋ถ„์ถœ(effusion)์€ ๊ธฐ์ฒด ๋ถ„์ž๊ฐ€ ์•„์ฃผ ์ž‘์€ ๊ตฌ๋ฉ์„ ํ†ตํ•ด ์ง„๊ณต์œผ๋กœ ๋น ์ ธ๋‚˜๊ฐ€๋Š” ํ˜„์ƒ์ž…๋‹ˆ๋‹ค. ๊ทธ๋ ˆ์ด์—„ ๋ฒ•์น™์— ๋”ฐ๋ฅด๋ฉด ๊ฐ€๋ฒผ์šด ๊ธฐ์ฒด์ผ์ˆ˜๋ก ๋” ๋น ๋ฅด๊ฒŒ ๋ถ„์ถœ๋˜๋ฉฐ, ๋ถ„์ถœ ์†๋„๋Š” ๊ธฐ์ฒด ๋ชฐ์งˆ๋Ÿ‰์˜ ์ œ๊ณฑ๊ทผ์— ๋ฐ˜๋น„๋ก€ํ•ฉ๋‹ˆ๋‹ค. ์ด ๊ณ„์‚ฐ๊ธฐ๋Š” ๊ทธ๋ ˆ์ด์—„ ๋ฒ•์น™์„ ์ ์šฉํ•˜์—ฌ, ๊ธฐ์ค€ ๊ธฐ์ฒด(๊ธฐ์ฒด 2)์˜ ๋ถ„์ถœ ์†๋„์™€ ๋‘ ๊ธฐ์ฒด์˜ ๋ชฐ์งˆ๋Ÿ‰์„ ์•Œ ๋•Œ ํ•œ ๊ธฐ์ฒด(๊ธฐ์ฒด 1)์˜ ๋ถ„์ถœ ์†๋„๋ฅผ ๊ตฌํ•ด ์ค๋‹ˆ๋‹ค.

Two gas containers each with a tiny pinhole, light fast molecules escaping quickly versus heavy slow molecules escaping slowly
Effusion: gas molecules escaping through a tiny pinhole, with lighter molecules escaping faster.

์‚ฌ์šฉ ๋ฐฉ๋ฒ•

๊ธฐ์ฒด 2์˜ ์•Œ๋ ค์ง„ ๋ถ„์ถœ ์†๋„(rateโ‚‚), ๊ธฐ์ฒด 1์˜ ๋ชฐ์งˆ๋Ÿ‰(Mโ‚), ๊ธฐ์ฒด 2์˜ ๋ชฐ์งˆ๋Ÿ‰(Mโ‚‚)์„ ์ž…๋ ฅํ•˜์„ธ์š”. ๋ชฐ์งˆ๋Ÿ‰์€ ๋ชจ๋‘ g/mol ๋‹จ์œ„์ž…๋‹ˆ๋‹ค. ๊ณ„์‚ฐ๊ธฐ๋Š” rateโ‚‚์™€ ๋™์ผํ•œ ๋‹จ์œ„๋กœ rateโ‚์„ ๋Œ๋ ค์ฃผ๋ฉฐ, ๋‹จ์œ„๊ฐ€ ์—†๋Š” ์†๋„๋น„ \(r_1/r_2\)๋„ ํ•จ๊ป˜ ์ œ๊ณตํ•ฉ๋‹ˆ๋‹ค.

๊ณต์‹ ํ’€์ด

๊ทธ๋ ˆ์ด์—„ ๋ฒ•์น™์€ ๋‹ค์Œ๊ณผ ๊ฐ™์ด ํ‘œํ˜„๋ฉ๋‹ˆ๋‹ค.

$$\frac{r_1}{r_2} = \sqrt{\frac{M_2}{M_1}}$$

์†๋„์— ๋น„ํ•ด ๋ชฐ์งˆ๋Ÿ‰์˜ ์œ„์น˜๊ฐ€ ์„œ๋กœ ๋ฐ”๋€Œ์–ด ์žˆ๋‹ค๋Š” ์ ์— ์ฃผ๋ชฉํ•˜์„ธ์š”. ์ฆ‰, ๋” ๊ฐ€๋ฒผ์šด ๊ธฐ์ฒด(M์ด ์ž‘์€ ๊ธฐ์ฒด)๊ฐ€ ๋” ๋†’์€ ์†๋„๋ฅผ ๊ฐ€์ง‘๋‹ˆ๋‹ค. ๋ฏธ์ง€์ˆ˜๋ฅผ ๊ตฌํ•˜๋„๋ก ์‹์„ ์ •๋ฆฌํ•˜๋ฉด ๋‹ค์Œ์ด ๋ฉ๋‹ˆ๋‹ค.

$$r_1 = r_2 \sqrt{\frac{M_2}{M_1}}$$

\(M_1 < M_2\)์ด๋ฉด ์ œ๊ณฑ๊ทผ ๊ฐ’์ด 1๋ณด๋‹ค ์ปค์ง€๋ฏ€๋กœ ๊ธฐ์ฒด 1์ด ๊ธฐ์ฒด 2๋ณด๋‹ค ๋น ๋ฅด๊ฒŒ ๋ถ„์ถœ๋ฉ๋‹ˆ๋‹ค.

Graham's law relationship shown as inverse relation between effusion rate and square root of molar mass
Graham's Law: a gas's effusion rate is inversely proportional to the square root of its molar mass.

๊ณ„์‚ฐ ์˜ˆ์‹œ

ํ—ฌ๋ฅจ(\(M_1 = 4.0026\) g/mol)๊ณผ ์‚ฐ์†Œ(\(M_2 = 31.998\) g/mol)๋ฅผ ๋น„๊ตํ•˜๊ณ , ์‚ฐ์†Œ์˜ ๋ถ„์ถœ ์†๋„๋ฅผ \(r_2 = 1\)์ด๋ผ๊ณ  ํ•ฉ์‹œ๋‹ค. ๊ทธ๋Ÿฌ๋ฉด ๋‹ค์Œ์ด ๋ฉ๋‹ˆ๋‹ค.

$$r_1 = 1 \times \sqrt{\frac{31.998}{4.0026}} = \sqrt{7.994} \approx 2.827$$

ํ—ฌ๋ฅจ์€ ์‚ฐ์†Œ๋ณด๋‹ค ์•ฝ 2.83๋ฐฐ ๋น ๋ฅด๊ฒŒ ๋ถ„์ถœ๋˜๋Š”๋ฐ, ์ด๋Š” ํ—ฌ๋ฅจ์˜ ํ›จ์”ฌ ์ž‘์€ ๋ชฐ์งˆ๋Ÿ‰๊ณผ ์ž˜ ๋“ค์–ด๋งž๋Š” ๊ฒฐ๊ณผ์ž…๋‹ˆ๋‹ค.

์ž์ฃผ ๋ฌป๋Š” ์งˆ๋ฌธ

๋ถ„์ถœ(effusion)์€ ํ™•์‚ฐ(diffusion)๊ณผ ๊ฐ™์€๊ฐ€์š”? ๋‘˜์€ ์„œ๋กœ ๊ด€๋ จ์ด ์žˆ์œผ๋ฉฐ, ๊ทธ๋ ˆ์ด์—„ ๋ฒ•์น™์€ ๊ทผ์‚ฌ์ ์œผ๋กœ ์–‘์ชฝ ๋ชจ๋‘์— ์ ์šฉ๋ฉ๋‹ˆ๋‹ค. ๋‹ค๋งŒ ์—„๋ฐ€ํžˆ ๋งํ•˜๋ฉด ์ž‘์€ ๊ตฌ๋ฉ์„ ํ†ตํ•œ ๋ถ„์ถœ ํ˜„์ƒ์„ ์„ค๋ช…ํ•˜๋Š” ๋ฒ•์น™์ž…๋‹ˆ๋‹ค.

rateโ‚‚๋Š” ์–ด๋–ค ๋‹จ์œ„๋กœ ์ž…๋ ฅํ•ด์•ผ ํ•˜๋‚˜์š”? ์ผ๊ด€์„ฑ๋งŒ ์œ ์ง€๋˜๋ฉด ์–ด๋–ค ์†๋„ ๋‹จ์œ„๋“  ์‚ฌ์šฉํ•  ์ˆ˜ ์žˆ์Šต๋‹ˆ๋‹ค(mol/s, ๋ถ€ํ”ผ/์‹œ๊ฐ„, ๋˜๋Š” ๋‹จ์ˆœํžˆ ์ƒ๋Œ€๊ฐ’ 1 ๋“ฑ). rateโ‚์€ ์ž…๋ ฅํ•œ ๊ฒƒ๊ณผ ๋™์ผํ•œ ๋‹จ์œ„๋กœ ๋ฐ˜ํ™˜๋ฉ๋‹ˆ๋‹ค.

์™œ ๋ชฐ์งˆ๋Ÿ‰์ด ๋ฐ˜๋Œ€๋กœ ๋“ค์–ด๊ฐ€๋‚˜์š”? ๊ฐ™์€ ์˜จ๋„์—์„œ ํ‰๊ท  ์šด๋™ ์—๋„ˆ์ง€๊ฐ€ ๊ฐ™์œผ๋ฏ€๋กœ ๊ฐ€๋ฒผ์šด ๋ถ„์ž์ผ์ˆ˜๋ก ๋” ๋น ๋ฅด๊ฒŒ ์›€์ง์ž…๋‹ˆ๋‹ค. ๋”ฐ๋ผ์„œ \(M_1\)์ด ์ž‘์„์ˆ˜๋ก ๋” ํฐ ์†๋„๊ฐ€ ๋‚˜์˜ต๋‹ˆ๋‹ค.

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